Publikationen

Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

Autor(en)
Stefan Wild, Michael Fickert, Aleksandra Mitrovic, Vicent Lloret, Christian Neiss, José Alejandro Vidal-Moya, Miguel Ángel Rivero-Crespo, Antonio Leyva-Pérez, Katharina Werbach, Herwig Peterlik, Mathias Grabau, Haiko Wittkämper, Christian Papp, Hans Peter Steinrück, Thomas Pichler, Andreas Görling, Frank Hauke, Gonzalo Abellán, Andreas Hirsch
Abstrakt

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

Organisation(en)
Dynamik Kondensierter Systeme, Fakultätszentrum für Nanostrukturforschung, Elektronische Materialeigenschaften
Journal
Angewandte Chemie - International Edition
Band
58
Seiten
5763-5768
ISSN
1433-7851
DOI
https://doi.org/10.1002/anie.201811181
Publikationsdatum
01-2019
Publikationsstatus
Elektronische Veröffentlichung vor Drucklegung
Peer-reviewed
Ja
ÖFOS 2012
104026 Spektroskopie
ASJC Scopus Sachgebiete
Catalysis, Chemistry(all)
Link zum Portal
https://ucris.univie.ac.at/portal/de/publications/lattice-opening-upon-bulk-reductive-covalent-functionalization-of-black-phosphorus(e9097d37-14d5-43f8-8ca9-b98433d92374).html